Search results for "density [astrophysics]"

showing 10 items of 561 documents

In vitro effects of aminobisphosphonates on Vgamma9Vdelta2 T cell activation and differentiation.

2006

In this study we have evaluated the in vitro effects of four different aminobisphosphonates, alendronate, risedronate, neridronate and zoledronate, on Vγ9Vδ2 T cell activation and differentiation. All tested aminobisphosphonates induce an IL-2-dependent activation and expansion of Vγ9Vδ2 T lymphocytes in primary PBMC cultures of healthy donors. Most notably, they also determine a different distribution of Vγ9Vδ2 T cell subsets, with decrease of Tnaive and TCM cells and increase of TEM and TEMRA Vγ9Vδ2 cells, indicating that in vitro treatment with aminobisphosphonates induces Vγ9Vδ2 T lymphocytes to differentiate towards an effector/cytotoxic phenotype. Accordingly, Vγ9Vδ2 T lymphocytes cu…

Cell SurvivalT cellT-LymphocytesImmunologyLymphocyte ActivationPeripheral blood mononuclear cellMonocytesFlow cytometry03 medical and health sciencesInterferon-gamma0302 clinical medicinemedicineImmunology and AllergyCytotoxic T cellHumansCytotoxicityImage CytometryPharmacologymedicine.diagnostic_testBone Density Conservation AgentsDiphosphonatesChemistryEffectorCell DifferentiationFlow CytometryPhenotypeIn vitromedicine.anatomical_structure030220 oncology & carcinogenesisCancer research030215 immunologyInternational journal of immunopathology and pharmacology
researchProduct

Applications of the Conceptual Density Functional Theory Indices to Organic Chemistry Reactivity.

2016

Indexación: Web of Science Theoretical reactivity indices based on the conceptual Density Functional Theory (DFT) have become a powerful tool for the semiquantitative study of organic reactivity. A large number of reactivity indices have been proposed in the literature. Herein, global quantities like the electronic chemical potential μ, the electrophilicity ω and the nucleophilicity N indices, and local condensed indices like the electrophilic and nucleophilic Parr functions, as the most relevant indices for the study of organic reactivity, are discussed. http://www.mdpi.com/1420-3049/21/6/748

Chemical PhenomenaNucleophilicityChemistry OrganicPharmaceutical ScienceElectronsnucleophilicityReview010402 general chemistry01 natural sciencesreactivity indicesAnalytical ChemistryMolecular electron density theorylcsh:QD241-441Reactivity indicesNucleophilelcsh:Organic chemistryconceptual DFTParr functionsComputational chemistryDrug DiscoveryOrganic chemistryReactivity (chemistry)Physical and Theoretical ChemistryElectrophilicity010405 organic chemistryChemistryOrganic Chemistrymolecular electron density theory0104 chemical sciencesChemistry (miscellaneous)Conceptual DFTElectrophileMolecular MedicineQuantum TheoryDensity functional theoryelectrophilicityMolecules (Basel, Switzerland)
researchProduct

Edible Arabinoxylan-Based Films. 1. Effects of Lipid Type on Water Vapor Permeability, Film Structure, and Other Physical Characteristics

2002

Arabinoxylans (AX) are natural fibers extracted from maize bran, an industrial byproduct. To promote this polymer as a food ingredient, development of edible coatings and films had been proposed. Indeed, composite arabinoxylan-based films were prepared by emulsifying a fat: palmitic acid, oleic acid, triolein, or a hydrogenated palm oil (OK35). Lipid effects on water vapor permeability (WVP), surface hydrophobicity (contact angles), lipid particle size, and mechanical properties were investigated. Results showed that OK35-AX emulsion films had the lowest WVP. Emulsified films presented a bimodal particle size distribution; however, the smallest particle mean diameter (0.54 microm) was obser…

Chemical PhenomenaPolymersSurface PropertiesPalmitic AcidPalm OilZea maysPermeabilityContact anglechemistry.chemical_compoundArabinoxylanPlant OilsOrganic chemistryTrioleinParticle SizeChemistry PhysicalChemistryFood PackagingWaterGeneral ChemistryLow-density polyethyleneOleic acidChemical engineeringEmulsionFood TechnologyEmulsionsXylansParticle sizeLipid particleGeneral Agricultural and Biological SciencesTrioleinOleic AcidJournal of Agricultural and Food Chemistry
researchProduct

Ab initio modelling of the effects of varying Zr (Ti) concentrations on the atomic and electronic properties of stoichiometric PZT solid solutions

2017

Abstract Lead zirconate titanate Pb(ZrxTi1−x)O3 solid solution is considered as one of the most advanced ferroelectric and piezoelectric materials. Consequent variation of Zr (Ti) concentrations significantly affects the atomic and electronic properties of PZT structures. To perform ab initio modelling of different morphologies for lead zirconate titanate, we are using approach of hybrid density functional B3PW as implemented in CRYSTAL14 computer code. In this study, we are performing large-scale calculations of such PZT parameters as optimized lattice constants, atomic charges and bond populations, as well as band structure (e.g., band gap) and density of states.

ChemistryBand gapAb initioAnalytical chemistry02 engineering and technology021001 nanoscience & nanotechnologyCondensed Matter PhysicsLead zirconate titanate01 natural sciencesBiochemistryFerroelectricityComputer Science::OtherCondensed Matter::Materials Sciencechemistry.chemical_compoundLattice constantComputational chemistry0103 physical sciencesDensity of statesPhysical and Theoretical Chemistry010306 general physics0210 nano-technologyElectronic band structureSolid solutionComputational and Theoretical Chemistry
researchProduct

A current source density analysis of field potentials evoked in slices of visual cortex

1987

The method of one-dimensional current source density (CSD) analysis was applied to field potentials recorded from 350 microns thick slices of the primary visual cortex of rats and cats. Field potentials were elicited by stimulation of the white matter and recorded along trajectories perpendicular to the cortical layers at spatial intervals of 25 to 50 microns. The resulting CSD distributions resembled closely those recorded from the cat visual cortex "in vivo". The responses with the shortest latency were distinct sinks in layers IV and VI probably reflecting monosynaptic EPSP's from specific thalamic afferents. From layer IV activity was relayed along three major routes: 1. to the supragra…

ChemistryGeneral NeuroscienceAge FactorsRats Inbred StrainsStimulationIn Vitro TechniquesStimulus (physiology)Current sourceElectric StimulationRatsWhite matterVisual cortexmedicine.anatomical_structureIn vivoDensity analysisCatsReaction TimeExcitatory postsynaptic potentialmedicineBiophysicsAnimalsEvoked Potentials VisualNeuroscienceVisual CortexExperimental Brain Research
researchProduct

The chloro‐substituent enhances performance of 2,4‐bis (imino)pyridylchromium catalysts yielding highly linear polyethylene

2020

The five unsymmetrical 2‐[1‐(2,4‐dibenzhydryl‐6‐chlorophenylimino)ethyl]‐6‐[1‐(arylimino)ethyl]pyridine compounds (aryl: 2,6‐Me2Ph L1 , 2,6‐Et2Ph L2 , 2,6‐i Pr2Ph L3 , 2,4,6‐Me3Ph L4 and 2,6‐Et2–4‐MePh L5 ) were prepared and characterized with FT‐IR and 1H/13C NMR spectroscopy as well as elemental analysis. The treatment of L1 – L5 with CrCl3·3THF affords the corresponding chromium chloride complexes (Cr1 – Cr5 ) in excellent yields. The molecular structures of Cr2 and Cr3 characterized by X‐ray diffraction show a distorted octahedral geometry with three nitrogen atoms and three chlorine atoms around the metal center. On activation with either MAO or MMAO, Cr1 – Cr5 collectively display hig…

ChemistrySubstituentGeneral Chemistryethylene polymerizationCatalysisinfluence of chloro‐substituentInorganic ChemistryLinear low-density polyethyleneBis (imino)pyridinechemistry.chemical_compoundEthylene polymerizationPolymer chemistrychromium precatalysthighly linear polyethyleneApplied Organometallic Chemistry
researchProduct

Atomic and electronic structure of the corundum (0001) surface: comparison with surface spectroscopies

1997

Abstract The electronic structure and geometry of the Al-terminated corundum (0001) surface were studied using a slab model within the ab-initio Hartree-Fock technique. The distance between the top Al plane and the next O basal plane is found to be considerably reduced on relaxation (by 0.57 A, i.e. by 68% of the corresponding interlayer distance in the bulk). An interpretation of experimental photoelectron spectra (UPS He I) and metastable impact electron spectra (MIES) is given using the calculated total density of states of the slab and the projections to the atoms, atomic orbitals, and He 1s floating atomic orbital at different positions above the surface. Calculated projected densities…

ChemistrySurfaces and InterfacesElectronic structureCondensed Matter PhysicsElectron spectroscopySpectral lineSurfaces Coatings and FilmsAtomic orbitalX-ray photoelectron spectroscopyMetastabilityPhysics::Atomic and Molecular ClustersMaterials ChemistryDensity of statesRelaxation (physics)Physics::Atomic PhysicsAtomic physicsSurface Science
researchProduct

Cluster-model density functional study of a W–Cu(100) STM junction

1999

Abstract In this article, we investigate the electronic properties of different clusters modelling a tungsten tip, the Cu(1 0 0) surface and interacting W–Cu(1 0 0) systems in STM configuration. Electronic structure calculations are carried out within the LDA approximation of the Density Functional Theory (DFT). Both integrated (densities of states) and local properties (electronic density and electrostatic potential) are considered. The study is performed for top and hollow surface sites and two different tip–sample separations.

Chemistrychemistry.chemical_elementHeterojunctionGeneral ChemistryElectronic structureTungstenCondensed Matter PhysicsMolecular physicsTransition metalComputational chemistryDensity of statesCluster (physics)General Materials ScienceDensity functional theoryElectronic densityJournal of Physics and Chemistry of Solids
researchProduct

Associations Between Built Environment Characteristics and Walking in Older Adults in a High-Density City: A Study From a Chinese Megacity

2020

The built environment is an important factor affecting physical activity, especially walkability. Walkability is used to characterize the user friendliness of outdoor physical activity. However, studies on walkability and physical activity are mainly concentrated on low-density Western cities. Study on the walkability of high-density cities in Asia, especially with the elderly, is seriously lacking. And walkability is often used as a composite indicator. This study mainly re-examines the relationship between the common indicators of walkability (population density, street connectivity, land-use mix, and retail density), transport-related walking, and leisure-time walking with older adults i…

ChinaAsiaPhysical activityUser friendlinesswalking03 medical and health sciences0302 clinical medicineResidence CharacteristicsEnvironmental healthHumansElderly peopleleisure-time walking030212 general & internal medicineBuilt EnvironmentCitiesolder adultsBuilt environmentAgedOriginal Researchwalkabilitylcsh:Public aspects of medicine030503 health policy & servicesPublic Health Environmental and Occupational Healthlcsh:RA1-1270Middle AgedComposite indicatorhigh-density citytransport-related walkingMegacityGeographyWalkabilityEnvironment DesignPublic Health0305 other medical sciencehuman activitiesStatistical correlationFrontiers in Public Health
researchProduct

Identification of off-flavor compounds in high-density polyethylene (HDPE) with different amounts of abscents

1998

The use of synthetic pipes for drinking water distribution has increased. High desnity polyethylene (HPDE) is preferred because of its favorable mechanical properties, ease of handling during manufacturing, and low permeability to external contaminants. Off-flavor drinking water is a problem with plastic pipes. The compounds causing off-flavors are mainly carbonyl compounds. A combined zeolite called Abscents is used to eliminate odors and to remove odor-causing compounds. In this study, four different amounts of Abscents were added to raw HDPE pellets, and the influence on the off-flavor properties were analyzed. When the maximum amount of Abscents was added, almost all the carbonyl compou…

ChromatographyPolymers and PlasticsPelletsConcentration effectGeneral ChemistryPolyethylenechemistry.chemical_compoundchemistryOdorMaterials ChemistryHigh-density polyethyleneGas chromatographyZeoliteFlavorPolymer Engineering & Science
researchProduct